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HEDP - 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid HEDP - 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid

HEDP - 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid

CAS No. 2809-21-4        & ;nbs p;           ; ;              

Properties:

HEDP is an organophosphoric acid corrosion inhibitor. It can chelate with Fe, Cu, and Zn ions to form stable chelating compounds. It can dissolve the oxidized materials on these metals’ surfaces. HEDP shows excellent scale and corrosion inhibition effects under temperature 250℃. HEDP has good chemical stability under high pH value, hard to be hydrolyzed, and hard to be decomposed under ordinary light and heat conditions. Its acid/alkali and chlorine oxidation tolerance are better than that of other organophosphoric acids (salt). HEDP can react with metal ions in water system to form hexa-element chelating complex, with calcium ion in particular. Therefore, HEDP has good antiscale and visible threshold effects. When built together with other water treatment chemicals, it shows good synergistic effects.

The solid state of HEDP is crystal powder, suitable for usage in winter and freezing districts. Because of its high purity, it can be used as cleaning agent in electronic fields and as additives in daily chemicals. 

Specification:

items

index

Appearance

Colorless or light yellow transparent liquid

White crystal powder

Active contentHEDP)%

58.0-62.0

89.0 min

Phosphorous acidas PO33-%

2.0 max

0.5 max

Phosphoric acid asPO43- %

0.8 max

0.5 max

Chloride (as Cl-)%

0.01 max

0.01 max

pH1 solution

2 max

2 max

Density 20℃g/cm3

1.40

Fe ion ppm

10 max

20 max

Colour APHA (Hazen)

40 max

Usage:

HEDP is used as scale and corrosion inhibition in circulating cool water system, oil field and low-pressure boilers in fields such as electric power, chemical industry, metallurgy, fertilizer, etc.. In light woven industry, HEDP is used as detergent for metal and nonmetal. In dyeing industry, HEDP is used as peroxide stabilizer and dye-fixing agent; In non-cyanide electroplating, HEDP is used as chelating agent. The dosage of 1-10mg/L is preferred as scale inhibitor, 10-50mg/L as corrosion inhibitor, and 1000-2000mg/L as detergent. Usually, HEDP is used together with polycarboxylic acid.

Package and Storage:

HEDP liquid: Normally In 250kg net Plastic Drum, IBC drum can also be used as required HEDP solid: 25kg inner liner polyethylene (PE) bag, outer plastic woven bag, or confirmed by clients.

Storage for ten months in room shady and dry place.

Safety Protection:

Acidity, Avoid contact with eye and skin, once contacted, flush with water. 

 

[Related Categories: Organic Acid, Water Treatment ]
[Related Keywords: HEDP, water treatment chemicals, corrosion inhibitor, chemical product, circulating cool water system, organophosphoric salts, bactericide and algicide, polycarboxylic antiscale, dispersant ]
Amino Trimethylene Phosphonic Acid (ATMP) Amino Trimethylene Phosphonic Acid (ATMP)

Amino Trimethylene Phosphonic Acid (ATMP)

CAS No. 6419-19-8        & ; ;nbs p;           ; ; ;                     & amp; amp; nbsp;        

 

Properties:

ATMP has excellent chelation, low threshold inhibition and lattice distortion ability. It can prevent scale formation, calcium carbonate in particular, in water system. ATMP has good chemical stability and is hard to be hydrolyzed in water system. At high concentration, it has good corrosion inhibition.

ATMP is used in industrial circulating cool water system and oilfield water pipeline in fields of thermal power plant and oil refinery plant. ATMP can decrease scale formation and inhibit corrosion of metal equipment and pipeline. ATMP can be used as chelating agent in woven and dyeing industries and as metal surface treatment agent.

The solid state of ATMP is crystal powder, soluble in water, easily deliquescence, suitable for usage in winter and freezing districts. Because of its high purity, it can be used in woven & dyeing industries and as metal surface treatment agent. 

Specification:

items

index

Appearance

Colorless or light yellow transparent liquid

White crystal powder

Active acid %

48.0-52.0

95 min

Chloride (as Cl-)%

2.0(or1.0) min

1.0 min

pH value1 solution

2.0 max

2.0 max

Fe (as Fe3+) (ppm)

20

20

Density 20℃g/cm3

1.33 min

Colour APHA (Hazen)

40 max

Usage:

ATMP is usually used together with organophosphoric acid, polycarboxylic acid and salt to built all organic alkaline water treatment agent. ATMP can be used in many different circulating cool water system. The dosage of 1-20mg/L is recommended. As corrosion inhibitor, the dosage of 20-60mg/L is preferred.

Package and Storage:

ATMP liquid: Normally In 250kg net Plastic Drum, IBC drum can also be used as required ATMP solid: 25kg inner liner polyethylene (PE) bag, outer plastic woven bag, or confirmed by clients.

Storage for ten months in room shady and dry place.

Safety Protection:

Acidity, Avoid contact with eye and skin, once contacted, flush with water.

 

[Related Categories: Water Treatment, Organic Acid ]
[Related Keywords: dispersant, polycarboxylic antiscale, bactericide and algicide, organophosphoric salts, circulating cool water system, chemical product, corrosion inhibitor, water treatment chemicals, ATMP ]
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Carbomer974 Carbomer974

Product

Carbomer974

CAS

54182-57-9

Specification

HY-II

Formula

- [-CH2-CH-]N-COOH

Acidity

2.5-3.5

Heavy metal

20ppm

Viscosity

30500-39400mpa.s

Drying

2.0%

Content  Measurement

56%-68%

Package

20KG/CARTON

Usage:

It is used for local drug delivery system. It is used for making the thick gels, emulsions, suspensions at high Viscosity. slow-release material, material of controlled-release drug

Character:

White loose power, Hygroscopicity,little ordor, good effect of Thickening ,permanent stability at high Viscosity, short reflux in aqueous solution

 

 

[Related Categories: Chemical Additives, Auxiliary ]
[Related Keywords: dispersant, lubricant, chemical auxiliaries ]
Carbomer1342 Carbomer1342

Product

Carbomer1342

CAS

54182-57-9

Specification

HY-IV

Formula

- [-CH2-CH-]N-COOH

Acidity

2.5-3.5

Heavy metal

20ppm

Viscosity

20000-40000mpa.s

Drying

2.0%

Content  Measurement

56%-68%

Package

20KG/CARTON

Usage:

It is usded for local drug delivery system. In the presence of electrolyte , it will be a good rheology modifier, polymer emulsification, In the application of topical formulations, it is used as a carrier matrix, and for making suppositories, creams, ointments

 

Character:

white loose power, Hygroscopicity,little ordor, High thickening effect, It  can produce crystal clear water or alcohol-water gel , and has strong ability of  anti-ion.

 

[Related Categories: Chemical Additives, Auxiliary ]
[Related Keywords: dispersant, lubricant, chemical auxiliaries ]
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Carbomer980 Carbomer980

Product

Carbomer980

CAS

54182-57-9

Specification

HY-V

Formula

- [-CH2-CH-]N-COOH

Acidity

2.5-3.5

Heavy metal

20ppm

Viscosity

4000-100000mpa.s

Drying

2.0%

Content  Measurement

56%-68%

Package

20KG/CARTON

Usage:

It is used for local drug delivery system, crystal clarity gels, water or alcohol solvent. In the application of topical formulations, it is used as a carrier matrix, and for making suppositories, creams, ointments, etc. This product has good suspension capacity.It is moslty used in oral suspension

 

Character:

white loose power, Hygroscopicity,little ordor, high viscosity and be Suitable for making gel products,and as slow-release material, material of controlled-release drug

 

 

 

 

 

[Related Categories: Chemical Additives, Auxiliary ]
[Related Keywords: dispersant, lubricant, chemical auxiliaries ]
Carbomer934P Carbomer934P

Product

Carbomer934P

CAS

54182-57-9

Specification

HY-III

Formula

- [-CH2-CH-]N-COOH

Acidity

2.5-3.5

Heavy metal

20ppm

Viscosity

29400-39400mpa.s

Drying

2.0%

Content  Measurement

56%-68%

Package

20KG/Carton

Usage:

Oral, local and new drug delivery systems, Release-controlled matrix tablets

Character

permanent stability at high Viscosity,  Be more suitable for oral pharmaceutical preparations due to residual solvents trace

 

 

 

 

 

 

 

[Related Categories: Chemical Additives, Auxiliary ]
[Related Keywords: dispersant, lubricant, chemical auxiliaries ]
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Carbomer934 Carbomer934

Product

Carbomer934

CAS

54182-57-9

Specification

HY-II

Formula

- [-CH2-CH-]N-COOH

Acidity

2.5-3.5

Heavy metal

20ppm

Viscosity

30500-39400mPa.s

Drying

2.0%

Content  Measurement

56%-68%

Package

20KG/Carton

Usage:

It is mostly used in local drug delivery system,and it is used for making the thick gels, emulsions, suspensions,and  slow-release material, material of  controlled-release drug

Character

good effect of Thickening ,permanent stability at high Viscosity, short reflux in aqueous solution

 

 

 

 

 

[Related Categories: Chemical Additives, Auxiliary ]
[Related Keywords: dispersant, lubricant, chemical auxiliaries ]
Carbomer941 Carbomer941

Product

Carbomer941

CAS

54182-57-9

Specification

HY-I

Formula

- [-CH2-CH-]N-COOH

Acidity

2.5-3.5

Heavy metal

20ppm

Viscosity

4000-11000mpa.s

Drying

2.0%

Content  Measurement

56%-68%

Package

20KG/Carton

Usage:

Making outer preparation, Gels, creams and coupling agent

Character

white loose power, Hygroscopicity,little ordor

 

 

 

 

 

 

[Related Categories: Chemical Additives, Auxiliary ]
[Related Keywords: dispersant, lubricant, chemical auxiliaries ]
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Carbomer940 Carbomer940

Product

Carbomer940

CAS

54182-57-9

Specification

HY-I

Formula

- [-CH2-CH-]N-COOH

Acidity

2.5-3.5

Heavy metal

20ppm

Viscosity

4000-11000mpa.s

Drying

2.0%

Content  Measurement

56%-68%

Package

20KG/CARTON

Usage:

Making outer preparation, Gels, creams and coupling agent

 

Character:

High viscosity and good thickening effect

 

 

[Related Categories: Chemical Additives, Auxiliary ]
[Related Keywords: dispersant, lubricant, chemical auxiliaries ]
PVPP PVPP

 

Product

PVPP

CAS

25249-54-1

CTFA

Crosslinking polyvingypyrrolidone

Quality standard

CP20005/USP30

Appearance

White podwer

Package

20KG/CARTON

 

Character:

White or nearly white powder with easy  hygroscopic and Liquidity. Odorless or slight odor. Not dissolve in water, alkali, acid and common organic solvents. It has been regarded as the best choice for high-end tablet disintegrating agents

 

Application:

PVPP is cross-linked compounds that is insoluble and is of high molecular weight .It also has excellent adsorption properties. PVP-P can be very safe and effective to be applied to beverages and wine industry

1 Completely insoluble in beer

2 Substantially increase in beer (wine, fruit juice, etc.) storage time in container

 

[Related Categories: Chemical Additives, Auxiliary ]
[Related Keywords: dispersant, lubricant, chemical auxiliaries ]
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Polyethylene Glycol 800(PEG800) Polyethylene Glycol 800(PEG800)

Product

PEG800

CAS

25322-68-3

Formula

HO(CH2CH2O)nH

Molecular weight

750-850

Heavy metal

5

Viscosity

2.2-2.4

PH Value

5-7

Freezing point

33-38

Arsenic salts(ppm)

≤3

Ignition Residue

≤0.2

Appearance

White paste

Package

25KG/CARTON

Clarity and color of solution:

Non-concentraded, not deeper than 2 # standard solution

 

Main function:

Oral use. It is mainly used for liquid solvents like oral solution ,and especially has a good hydrotropic for propolis in series of health-care products like oral propolis soft capsules.

 

Storage:

This product is non-toxic and flame retardant.Regarded as a general shipments of chemicals, it should be sealed and stored in dry place.

 

[Related Categories: Chemical Additives, Auxiliary ]
[Related Keywords: dispersant, lubricant, chemical auxiliaries ]
sell  polyethylene glycol 8000(PEG8000) sell polyethylene glycol 8000(PEG8000)

Product

PEG8000

CAS

25322-68-3

Formula

HO(CH2CH2O)nH

Molecular weight

180-220

Viscosity

16-20

PH Value

5-7

Freezing point

58-62

Ignition Residue

≤0.2

Appearance

White solid powder

Package

25KG/CARTON

Clarity and color of solution:

Non-concentraded, not deeper than 2 # standard solution

 

Main function:

PEG8000 is a kind of good coating materials,hydrophilic polishing materials, membranes and wall materials,plasticizers, lubricants and pills matrix. Be usded for the preparation of tablets, pills, capsules, microcapsules etc.

 

It can be used as organic media, a moisturizing agent for daily cosmetic industry, viscosity-adjusting agent, wetting agent for paper and pesticide

 

[Related Categories: Chemical Additives, Auxiliary ]
[Related Keywords: dispersant, lubricant, chemical auxiliaries ]
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Polyethylene Glycol 6000(PEG6000) Polyethylene Glycol 6000(PEG6000)

Product

PEG6000

CAS

25322-68-3

Formula

HO(CH2CH2O)nH

Molecular weight

5500-7500

Viscosity

11-16

PH Value

5-7

Ignition Residue

≤0.2

Appearance

White solid powder

Package

25KG/CARTON

Clarity and color of solution:

Non-concentraded, not deeper than 2 # standard solution

Storage:

This product is non-toxic and flame retardant.Regarded as a general shipments of chemicals, it should be sealed and stored in dry place.

 

 

 

 

[Related Categories: Pharmaceutical Chemicals ]
[Related Keywords: dispersant, lubricant, chemical auxiliaries ]
Polyacrylic Acid Sodium (PAAS) Polyacrylic Acid Sodium (PAAS)

Polyacrylic Acid Sodium (PAAS)

yCASz 9003-04-7 

Structural Formula:

\"Polyacrylic

Properties:

PAAS is innoxious and soluble in water, it can be used in situations of alkaline and high concentration without scale sediment. PAAS can disperse the microcrystals or microsand of calcium carbonate, calcium phosphate and calcium sulfate. PAAS is used as scale inhibition and dispersant for circulating cool water system, papermaking, weave, dyeing, ceramic, painting, etc.

Specification:

items index
Appearance Colorless or light yellow transparent liquid
Solid content % 30 min
Free monomer (CH2=CH-COOH) % 0.5 max
Density (20Ž)g/cm3 1.15 min
pH(1%  solution) 6.0~8.0

 Notes: Solid content 40%, 45% and 50% are also available

Usage:

PAAS can be used as scale inhibitor and dispersant in circulating cool water systems in power plants, iron & steel factories, chemical fertilizer plants, refineries and air conditioning systems. Dosage should be in accordance with water quality and equipment materials. When used alone, 2-15mg/L is preferred. When used as dispersant, the dosage should be determined by experiment.

Package and Storage:

25kg or 200kg in plastic barrel. Storage for ten months in room shady and dry place.

[Related Categories: High Polymers, Water Treatment ]
[Related Keywords: PAAS, WATER TREATMENT CHEMICAL, antiscalant, dispersant ]
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PAA--Polyacrylic Acid PAA--Polyacrylic Acid
CAS  9003-01-4

Properties:

PAA(Polyacrylic Acid) is innoxious and soluble in water, it can be used in situations of alkaline and high concentration without scale sediment. PAA(Polyacrylic Acid) can disperse the microcrystals or microsand of calcium carbonate, calcium phosphate and calcium sulfate. PAA(Polyacrylic Acid) is used as scale inhibitor and dispersant for circulating cool water system, papermaking, weave, dyeing, ceramic, painting, etc.

Specification:

items

index

Appearance

Colorless or light yellow transparent liquid

Solid content %

30 min

Free monomer (CH2=CH-COOH) %

0.5 max

Density (20 centigrade)g/cm3

1.09 min

pH(1%  solution)

3.0 max

40%, 50% PAA(Polyacrylic Acid) are also supplied.

Usage:

PAA(Polyacrylic Acid) can be used as scale inhibitor and dispersant in circulating cool water systems in power plants, iron & steel factories, chemical fertilizer plants, refineries and air conditioning systems. Dosage should be in accordance with water quality and equipment materials. When used alone, 1-15mg/L is preferred.

Package and Storage:

Normally In 200kg net Plastic Drum, IBC drum can also be used as required. Storage for one year in room shady and dry place.

[Related Categories: High Polymers ]
[Related Keywords: PAA, Polyacrylic Acid, water soluble polymer, dispersant, WATER TREATMENT CHEMICAL ]
AA/AMPS AA/AMPS
CAS 40623-75-4 Properties: AA/AMPS(Acrylic Acid-2-Acrylamido-2-Methylpropane) is the copolymer of acrylic acid and 2-acrylanmido-2-methylpropanesulfonic acid (AMPS). Due to including carboxylic group (scale inhibition and dispersion) and sulfonic acid group (strong polarity) in this copolymer, AA/AMPS(Acrylic Acid-2-Acrylamido-2-Methylpropane) has high calcium tolerance and good scale inhibition for calcium phosphate, calcium carbonate and zinc scale. When built with organophosphines, the synergic effect is obvious. AA/AMPS(Acrylic Acid-2-Acrylamido-2-Methylpropane) is suitable to be used in water quality of high pH and high alkaline, it is one of the ideal scale inhibitor and dispersant on high concentration index. Specification: Appearance Colorless or light yellow viscous liquid Solid content % 40 min Free monomer (as AA)% 0.8 max Density (20Ž)g/cm3 1.15 min pH(1% solution) 3.5-4.5 Viscosity mpa.s 90-200 Usage: AA/AMPS(Acrylic Acid-2-Acrylamido-2-Methylpropane) can be used as scale inhibitor and dispersant in open circulating cool water system, oilfield refill water system, metallurgy system and iron & steel plants to prevent sediment of ferric oxide. When built with organophosphorines and zinc salt, the suitable pH value is 7.0~9.5. AA/AMPS(Acrylic Acid-2-Acrylamido-2-Methylpropane) can also be used as dyeing auxiliaries for textile. Package and Storage: Normally In 250kg net Plastic Drum, IBC drum can also be used as required.Storage for ten months in room shady and dry place.
[Related Categories: High Polymers ]
[Related Keywords: AA/AMPS, Acrylic Acid-2-Acrylamido-2-Methylpropane Sulfonic Acid Copolymer, WATER TREATMENT CHEMICAL, water soluble polymer, dispersant ]
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MA/AA--Copolymer of Maleic and Acrylic Acid MA/AA--Copolymer of Maleic and Acrylic Acid
CAS 26677-99-6

Properties:

MA/AA(Copolymer of Maleic and Acrylic Acid) is a low molecular weight polyelectrolyte, a copolymer of maleic anhydride and acrylic acid. It has good dispersant performance against carbonate and scale inhibition for phosphate. it has good thermal stability, can be used under high temperature (300 centigrade). MA/AA(Copolymer of Maleic and Acrylic Acid) has good compatibility when used together with other agents. MA/AA(Copolymer of Maleic and Acrylic Acid) is widely used in low-pressure boiler, centralized heating, centralized air-conditioner and circulating cool system. It can also be used as chelating dispersants in woven and dyeing fields.

Specification:

items

Water treatment agent

Accessory detergent

Appearance

Clear brown liquid

amber transparent liquid

Solid content %

48 min

50 min

Free monomer (MA) %

9.0 max

5.0 max

Density (20 centigrade)g/cm3

1.18 min

1.18min

pH(1%  solution)

2.0~3.0

2.0}1.0

Usage:

MA/AA(Copolymer of Maleic and Acrylic Acid) is used in circulating cool water system, medium or lower pressure boiler and distillation system in which high temperature is usually encountered. MA/AA(Copolymer of Maleic and Acrylic Acid) can be used alone or together with other organic phosphates. When used together, the dosage of 2-10mg/L is preferred. The dosage for use as woven & dyeing and accessory detergent should be determined by experiments.

Package and Storage:

Normally In 250kg net Plastic Drum, IBC drum can also be used as required. Storage for one year in room shady and dry place.

Safety Protection:

Acidity, Avoid contact with eye and skin, once contacted, flush with water.

[Related Categories: High Polymers ]
[Related Keywords: MA/AA, Copolymer of Maleic and Acrylic Acid, WATER TREATMENT CHEMICAL, water soluble polymer, dispersant ]
Additives Additives
Defoamers: Non-silicone, Silicone, Powder Defoamer
Thickeners: For Solvent & Aqueous Systems
Preservatives: For Aqueous Inks & Paints
Thixotropice Agent: For Solvent & Aqueous Systems
Emulsifiers: For various industries
 
Application: Paints, Inks, Paper & Pulp, Starch, Lubricants, Pesticides
[Related Categories: Coatings, Paints & Coatings, Chemical Additives, Auxiliary, Others ]
[Related Keywords: Defoamer, Antifoam, Dispersing Agent, dispersant, Thickener ]
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Polycarboxylate Superplasticizer Polycarboxylate Superplasticizer

Keywords: polycarboxylate, polycarboxylic acid, copolymer, superplasticizers, water reducer, dispersant, concrete admixture, PC

 

 

Polycarbox ylate Superplasticizer (Polycarboxylate High-range Water Reducer) ----Third generation of concrete admixtures, fine comprehensive performance and green environmental protective products.

 

 

Specification (powder form):
Appearance: light grey powder
Water content: 5% Max.
Unit weight (g./L ): 600
PH value (20 deg. C., 20% solution): 6-8
Suggested mixed amount: 0.2% ( of the cementing material amount )

And (liquid form): solid content 40% solution

 


Packing: Powder: 25kgs/plastic sealed bag with liner;

Liquid: 1,000kgs/ tank

 

Storing: This powder is easy to absorb moisture in the air and protect it in sealed bag.

Storage period is 12 months.

 

Other concrete admixture we offer: Air Entraining Admixture, Waterproof Admixture, Antifreeze, Expansion Admixture, Early Strength Agent and Accelerator etc.

 

Superplasticizers / water reducer we supply mainly:

1. Polycarboxylate (Powder & Liquid)

2. Melamine sulfonate (Powder)

3. Naphthalene sulfonate...  (Powder)

4. Sodium Gluconate  (Powder)

5. Sodium Lignosulfonate  (Powder)

6. AminoSulfonic Acid Superplasticizer

7. Gypsum Retarder

[Related Categories: Chemical Additives, Auxiliary, Others ]
[Related Keywords: Polycarboxylate, polycarboxylic acid, Copolymer, superplasticizers, water reducer, dispersant, concrete admixture, PC ]
Antiscale and Dispersant for Reverse Osmosis Antiscale and Dispersant for Reverse Osmosis
TH-100 is a high-effective ant scale agent suitable for reverse osmosis (RO) Nan filtration (NF) and ultra filtration (UF) system. This product can inhibit the scale deposit on membrane surface improve the quantity and quality of water supply and lower the operation expanse. This product has the following properties: 1) Can effectively inhibit inorganic scale formation for a wide concentration span the largest permitted LSI value is 2.8 when no acid is added 2) Cannot flocculate with ferric oxide aluminum oxide or silica oxide to form suspended substance 3) Can effectively inhibit the pollution from ferric aluminum or heavy metals pollutants. The permitted ferric concentration for inlet water supply can reach to 8.0ppm 4) Can effectively inhibit the flocculate and deposit of silica the permitted silica concentration for condense side can reach to 290ppm 5) Can be used as CA, TFC, NF and UF membranes for reverse osmosis system 6) Has excellent solubility and stability 7) Be effective in range of pH value 5 - 10 Specifications: 1) Appearance: clear liquid, clear transparent liquid 2) Main contents: Macromolecular containing P, Macromolecular containing P 3) Decomposition product under high temperature: orthophosphate, orthophosphate 4) Total phosphoric acid (asPO43-) %: 20.0 5) Density (g/cm³): 1.08-0.05, 1.45- 0.05 6) PH value-1% water solution: 2.0-0.5, 2.0- 0.5 Package and storage: The original package of this product is 8 times condense liquid 25 gallon (27.55kg) per barrel. After diluting 8 times 220.4kg per barrel is obtained. Usage methods: The dosage is determined by water quality analysis and condition of reverse osmosis system. In the recommended range of dosage most scales can be under control such as calcium carbonate calcium sulfate barium sulfate ferric hydroxide aluminum hydroxide and silica. Water Tech. Other Price Terms: FOB Payment Terms: 30% deposit of T/T or L/C at sight Certification(s): CE, ISO9002Supply Ability: 30 x 20' FCL/month
[Related Categories: Water Treatment ]
[Related Keywords: antiscale, and, dispersant, for, reverse, osmosis ]
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